Supramolecular Organic and Organometallic Chemistry Centre
Selected Publications of the Organic Chemistry Group
Halogen-Bonded Organic Frameworks of Perfluoroiodo- and Perfluorodiiodobenzene with 2,2′,7,7′-Tetrapyridyl-9,9′-spirobifluorene,
L. Pop, I. G. Grosu,M. Miclăuş, N. D. Hădade, A. Pop, A. Bende, A. Terec, M. Bărboiu, I. Grosu, Cryst. Growth Des., 2021, 21, 1045-1054.
DOI: 10.1021/acs.cgd.0c01383
Effect of the mode of fixation of the thienyl rings on the electronic properties of electron acceptors based on indacenodithiophene (IDT),
N. Terenti, A. P. Crișan, S. Jungsuttiwong, N. D. Hădade, A. Pop, I. Grosu, J. Roncali, Dyes and Pigments, 2021, 187, 109116.
DOI: 10.1016/j.dyepig.2020.109116
Structure-properties relationships in triarylamine-based push-pull systems-C60 dyads as active material for single-material organic solar cells,
A. Bogdan, L. Szolga, G.-I. Giurgi, A. P. Crișan, D. Bogdan, S. Hadsadee, S. Jungsuttiwong, R. Po, I. Grosu, J. Roncali, Dyes and Pigments, 2021, 184, 108845.
DOI: 10.1016/j.dyepig.2020.108845
Synthesis, Structure and Supramolecular Properties of a Novel C3 Cryptand with Pyridine Units in the Bridges,
C. V. Crișan, A. Soran, A. Bende, N. D. Hădade, A. Terec, I. Grosu, Molecules, 2020, 25, 3789.
DOI: 10.3390/molecules25173789
Mono- and di-substituted pyrene-based donor-π-acceptor systems with phenyl and thienyl π-conjugating bridges,
M. I. Nan, E. Lakatos, G.-I. Giurgi, L. Szolga, R. Po, A. Terec, S. Jungsuttiwong, I. Grosu, J. Roncali, Dyes and Pigments, 2020, 181, 108527.
DOI: 10.1016/j.dyepig.2020.108527
Halogen Bonds (N---I) at Work: Supramolecular Catemeric Architectures of 2,7-Dipyridylfluorene with ortho-, meta-, or para-Diiodotetrafluorobenzene Isomers,
I. G. Grosu, L. Pop, M. Miclăuş, N. D. Hădade, A. Terec, A. Bende, C. Socaci, M. Bărboiu, I. Grosu, Cryst. Growth Des., 2020, 20, 3429-3441.
DOI: 10.1021/acs.cgd.0c00205
Structural diversity ranging from oligonuclear complexes to 1-D and 2-D coordination polymers generated by tetrasubstituted adamantane and spirobifluorene derivatives,
T. Mocanu, L. Pop, N. D. Hădade, S. Shova, S. Sorace, I. Grosu, M. Andruh, Eur. J. Inorg. Chem., 2019, 5025-5038.
DOI: 10.1002/ejic.201901167
C60-small arylamine push-pull dyads for single-material organic solar cells,
A. P. Diac, L. Szolga, C. Cabanetos, A. Bogdan, A. Terec, I. Grosu, J. Roncali, Dyes and Pigments, 2019, 171, 107748.
DOI: 10.1016/j.dyepig.2019.107748
“Geländer” macrocycles: Synthesis, chirality and racemisation barriers,
C. Lar, M. E. Moisă, E. Bogdan, A. Terec, N. D. Hădade, I. Grosu, L. David, C. Paizs, I. G. Grosu, Tetrahedron Lett., 2019, 60, 335-340.
DOI: 10.1016/j.tetlet.2018.12.047
Spirobifluorene-based Porous Organic Polymers as Efficient Porous Supports for Pd and Pt for Selective Hydrogenation,
M. M. Trandafir, L. Pop, N. D. Hădade, I. Hristea, C. M. Teodorescu, F. Krumeich, J. A. van Bokhoven, I. Grosu, V. I. Pârvulescu,, ChemCatChem , 2019, 11, 538-549.
DOI: 10.1002/cctc.201801247
The Dawn of Single Material Organic Solar Cells,
J. Roncali, I. Grosu, Adv. Sci. , 2019, 6, 1801026.
DOI: 10.1002/advs.201801026
A three-armed cryptand with triazine and pyridine units: Synthesis, structure and complexation with polycyclic aromatic compounds,
C. Lar, A. Woiczechowski-Pop, A. Bende, I. G. Grosu, N. Miklášová, E. Bogdan, N. D. Hădade, A. Terec, I. Grosu, Beil. J. Org. Chem., 2018, 14, 1370-1377.
DOI: 10.3762/bjoc.14.115
Naphthalenediimide – A Unique Motif in Macrocyclic and Interlocked Supramolecular Structures,
A. P. Diac, M. Matache, I. Grosu, N. D. Hădade, Adv. Synth. Catal., 2018, 360, 817-845.
DOI: 10.1002/adsc.201701362
Synthesis and ESI(+)-MS Complexation Studies of New 24-and 36-Membered Cyclic Peptides,
M. C. Pașcanu, E. Bogdan, A. Terec, I. Grosu, N. D. Hădade, Rev. Roum. Chim., 2017, 62, 349-355.
Modulating short tryptophan- and arginine-rich peptides activity by substitution with histidine,
M. Bacalum, L. Janosi, F. Zorila, A.-M. Țepes, C. Ionescu, E. Bogdan, N. D. Hădade, L. Crăciun, I. Grosu, I. Turcu, M. Radu, Biochim. Biophys. Acta - General Subjects, 2017, 1861, 1844-1854.
DOI: 10.1016/j.bbagen.2017.03.024
"Click" access to multilayer functionalized Au surface: A terpyridine patterning example,
F. A. Martin, D. Marconi, S. Neamțu, T. Radu, M. Florescu, R. Turcu, C. Lar, N. D. Hădade, I. Grosu, I. Turcu, Mat. Sci. Engin. C, 2017, 75, 1343-1350.
DOI: 10.1016/j.msec.2017.03.033
The nature of intermolecular interactions in pyridinium-anion-β-hexachlorocyclohexane molecular crystals,
I. G. Grosu, M. I. Rednic, M. Miclăuş, I. Grosu, A. Bende, Phys. Chem. Chem. Phys., 2017, 19, 20691-20698.
DOI: 10.1039/c7cp02911j
Coordination polymers constructed from tetrahedral-shaped adamantane tectons,
T. Mocanu, L. Pop, N. D. Hădade, S. Shova, I. Grosu, M. Andruh, CrystEngComm, 2017, 19, 27-31.
DOI: 10.1039/c6ce02146h
Inexpensive asorbents drived from coffee grounds for the treatment of wastewater,
O. Marincaș, V. Floare-Avram, I. Feher, D. Lazăr, C. Voica, I. Grosu, Anal. Lett., 2016, 2659-2670.
DOI: 10.1080/00032719.2015.1125913
An adamantane-based COF: stability, adsorption capability, and behaviour as a catalyst and support for Pd and Au for the hydrogenation of nitrostyrene,
M. M. Trandafir, L. Pop, N. D. Hădade, M. Florea, F. Neatu, C. M. Teodorescu, B. Duraki, J. A. van Bokhoven, I. Grosu, V. I. Pârvulescu, H. Garcia, Catal. Sci. Technol., 2016, 6, 8344-8354.
DOI: 10.1039/c6cy01631f
Supramolecular anion recognition by β-HCH,
M. I. Rednic, R. A. Varga, A. Bende, I. G. Grosu, M. Miclăuş, N. D. Hădade, A. Terec, E. Bogdan, I. Grosu, Chem. Commun., 2016, 52, 12322-12325.
DOI: 10.1039/C6CC06842A
Indenopyrans - synthesis and photoluminescence properties,
A. P. Diac, A.-M. Soran, A. Ţepeş, I. Grosu, A. Terec, J. Roncali, E. Bogdan, Beilstein J. Org. Chem., 2016, 12, 825-834.
DOI: 10.3762/bjoc.12.81
The 1,3-Dioxane Motif - a Useful Tool in Monitoring Molecular and Supramolecular Architectures,
E. Bogdan, N. D. Hădade, A. Terec, I. Grosu, Tetrahedron Lett., 2016, 57, 2683-2691.
DOI: 10.1016/j.tetlet.2016.05.024
Occurence of Charge-Assisted Hydrogen Bonding in Bis-amidine Complexes Generating Macrocycles,
L. Pop, N. D. Hădade, A. van der Lee, M. Barboiu, I. Grosu, Y.-M. Legrand, Cryst. Growth Des., 2016, 16, 3271-3278.
DOI: 10.1021/acs.cgd.6b00246
Supramolecular rulers enabling selective detection of pure short ssDNA via chiral self-assembly,
I. Kocsis, A. Rotaru, Y.-M. Legrand, I. Grosu, M. Barboiu, Chem. Commun., 2016, 52, 386-389.
DOI: 10.1039/C5CC08283H
Surface passivation of carbon nanoparticles with p-phenylenediamine towards photoluminescent carbon dots,
A. M. Crăciun, A. Diac, M. Focşan, C. Socaci, K. Magyari, D. Maniu, I. Mihalache, L. M. Veca, S. Aştilean, A. Terec, RSC Advances, 2016, 6, 56944-56951.
DOI: 10.1039/C6RA10127E
Exclusive Hydrophobic Self-Assembly of Adaptive Solid-State Networks of Octasubstituted 9,9'-Spirobifluorenes,
L. Pop, F. Dumitru, N. D. Hădade, Y.-M. Legrand, A. Van der Lee, M. Barboiu, I. Grosu, Org. Lett., 2015, 17, 3494-3497.
DOI: 10.1021/acs.orglett.5b01576
ADDA and ADADA systems based on triphenylamine as molecular donors for organic photovoltaics,
A. Diac, D. Demeter, S. Jungsuttiwong, I. Grosu, J. Roncali, Tetrahedron Lett., 2015, 56, 4607-4612.
DOI: 10.1016/j.tetlet.2015.05.103
CuAAC Synthesis of Tetragonal Building Blocks Decorated with Nucleobases,
L. Pop, M. L. Golban, N. D. Hădade, C. Socaci, I. Grosu, Synthesis, 2015, 47, 2799-2804.
DOI: 10.1055/s-0034-1378782
Cryptands with 2,4,6-tris(p-phenylene)-1,3,5-triazine central units and oligoethyleneoxide bridges: Synthesis, structure and complexation abilities,
C. V. Crişan, A. Terec, N. D. Hădade, I. Grosu, Tetrahedron, 2015, 71, 6888-6893.
DOI: 10.1016/j.tet.2015.07.019
Simple and versatile molecular donors for organic photovoltaics prepared by metal-free synthesis,
A. Diac, D. Demeter, M. Allain, I. Grosu, J. Roncali, Chem. Eur. J., 2015, 21, 1598-1608.
DOI: 10.1002/chem.201405425
Covalent conjugation of carbon dots with Rhodamine B and assessment of their photophysical properties,
A. Diac, M. Focsan, C. Socaci, A.-M. Găbudean, C. Farcău, D. Maniu, E. Vasile, A. Terec, L. M. Veca, S. Astilean, RSC Advances, 2015, 5, 77662-77669.
DOI: 10.1039/C5RA13161H
Thiophene-based macrocycles via the Suzuki-Miyaura cross coupling reaction,
A. Petran, A. Terec, E. Bogdan, A. Soran, E. Lakatos, I. Grosu, Tetrahedron, 2014, 70, 6803-6809.
DOI: 10.1016/j.tet.2014.07.061
Small molecular donors for organic solar cells obtained by simple and clean synthesis,
D. Demeter, S. Mohamed, A. Diac, I. Grosu, J. Roncali, ChemSusChem, 2014, 7, 1046-1050.
DOI: 10.1002/cssc.201301339
Self-sorting of dynamic metallosupramolecular libraries (DMLs) via metal-driven selection,
I. Kocsis, D. Dumitrescu, Y.-M. Legrand, A. Van Der Lee, I. Grosu, M. Barboiu, Chem. Commun., 2014, 50, 2621-2623.
DOI: 10.1039/C3CC49673B
Novel nucleobase-decorated tripodands: Synthesis and supramolecular properties,
M. L. Golban, V. Pascanu, N. D. Hǎdade, L. Pop, C. Socaci, I. Grosu, Synthesis, 2014, 1229-1235.
DOI: 10.1055/s-0033-1340833
Selective Host Molecules Obtained by Dynamic Adaptive Chemistry,
M. Matache, E. Bogdan, N. D. Hădade, Chem.-Eur. J., 2014, 20, 2106-2131.
DOI: 10.1002/chem.201303504
Synthesis of cryptands with di-yne units via acetylenic homocoupling reactions of C-3 tripodands,
V. Pascanu, M. Circu, C. Socaci, A. Terec, A. Soran, I. Grosu, Tetrahedron Lett., 2013, 54, 6133-6136.
DOI: 10.1016/j.tetlet.2013.09.007
Cryptands with 1,3,5-tris(1',3'-dioxan-2'-yl)-benzene units: synthesis and structural investigations,
M. Circu, A. Soran, N. D. Hadade, M. Rednic, A. Terec, I. Grosu, J. Org. Chem., 2013, 78, 8722-8729.
DOI: 10.1021/jo401432y
Macrocycles with a phenothiazine core: synthesis, structural analysis, and electronic properties,
I. Medrut, R. Turdean, R. Gropeanu, F. Pop, L. Toupet, N. D. Hădade, E. Bogdan, I. Grosu, Tetrahedron Lett., 2013, 54, 1107-1111.
DOI: 10.1016/j.tetlet.2012.12.068
Macrocycles with bithiophene units: synthesis, structure, and electrochemical properties,
D. Demeter, C. Lar, J. Roncali, I. Grosu, Tetrahedron Lett., 2013, 54, 1460-1462.
DOI: 10.1039/C3CC44391D
Luminogenic "clickable" lanthanide complexes for protein labeling,
N. Candelon, N. D. Hӑdade, M. Matache, J.-L. Canet, F. Cisnetti, D. P. Funeriu, L. Nauton, A. Gautier, Chem. Commun., 2013, 49, 9206-9208.
DOI: 10.1039/C3CC44391D
Unexpected Formation of N-(1-(2-Aryl-hydrazono)isoindolin-2-yl)benzamides and Their Conversion into 1,2-(Bis-1,3,4-oxadiazol-2-yl)benzenes,
C. C. Paraschivescu, M. Matache, C. Dobrotă, A. Nicolescu, C. Maxim, C. Deleanu, I. C. Fărcăşanu, N. D. Hădade, J. Org. Chem., 2013, 78, 2670-2679.
DOI: 10.1021/jo400023z
Cryptands and bismacrocycles with cyanuric and isocyanuric units: synthesis and structural investigations,
F. Pop, C. Socaci, A. Terec, E. Condamine, R. A. Varga, C. I. Raț, J. Roncali, I. Grosu, Tetrahedron, 2012, 68, 8581-8588.
DOI: 10.1016/j.tet.2012.07.100
Synthesis and Structural Analysis of some Podands with C-3 Symmetry,
A. Woiczechowski-Pop, I. L. Dobra, G. D. Roiban, A. Terec, I. Grosu, Synth. Commun., 2012, 42, 3579-3588.
DOI: 10.1080/00397911.2011.585732
Solid state supramolecular assemblies of triol podands through H-bonds,
M. Circu, V. Pascanu, A. Soran, B. Braun, A. Terec, C. Socaci, I. Grosu, CrystEngComm, 2012, 14, 632-639.
DOI: 10.1039/C1CE05971H
Reactivity of Unsaturated 5(4H)-Oxazolones with Hg(II) Acetate: Synthesis of Methyl N-Benzoylamino-3-arylacrylates,
G. D. Roiban, T. Soler, M. Contel, I. Grosu, C. Cativiela, M. Martinez, E. P. Urriolabeitia, Synth. Commun., 2012, 42, 195-203.
DOI: 10.1080/00397911.2010.523157
Regioselective Orthopalladation of (Z)-2-Aryl-4-Arylidene-5(4H)-Oxazolones: Scope, Kinetico-Mechanistic, and Density Functional Theory Studies of the C-H Bond Activation,
G. D. Roiban, E. Serrano, T. Soler, G. Aullon, I. Grosu, C. Cativiela, M. Martinez, E. P. Urriolabeitia, Inorg. Chem., 2011, 50, 8132-8140.
DOI: 10.1021/ic200564d
Cyclopenta[c]pyrans,
E. Bogdan, M. Tintas, I. Grosu, J. Heterocycl. Chem., 2011, 48, 747–762.
DOI: 10.1002/jhet.589
Geometric Enantiomerism in Cyclic Compounds: Chiral Dibrominated 1,3-Dioxanes,
C. Cismaş, N. Vanthuyne, H. Rispaud, R. A. Varga, E. Bogdan, C. Roussel, I. Grosu, Chirality, 2011, 23, 167-171.
DOI: 10.1002/chir.20895
Metal Ion Mediated Self-Assembly Directed Formation of Protein Arrays,
N. D. Bogdan, M. Matache, G.-D. Roiban, C. Dobrotă, V. M. Meier, D. P. Funeriu, Biomacromolecules, 2011, 12, 3400-3405.
DOI: 10.1021/bm200833k
Molecular Modeling of Phenothiazine Derivatives: Self-Assembling Properties,
A. Bende, I. Grosu, I. Turcu, J. Phys. Chem. A, 2010, 114, 12479-12489.
DOI: 10.1021/jp105012g
Electropolymerizable 3Dπ-conjugated architectures with ethylenedioxythiophene (EDOT) end-groups as precursors of electroactive conjugated networks,
F. Piron, Ph. Leriche, I. Grosu, J. Roncali, J. Mater. Chem., 2010, 20, 10260–10268.
DOI: 10.1039/C0JM01873B
Orthopalladation of (Z)-2-Aryl-4-Arylidene-5(4H)-Oxazolones. Structure and Functionalization,
D. G. Roiban, E. Serrano, T. Soler, M. Contel, I. Grosu, C. Cativiela, E. P. Urriolabeitia, Organometallics, 2010, 29, 1428-1435.
DOI: 10.1021/om901068f
Synthesis and electronic properties of terthienyls β-substituted by (thienyl)cyanovinylene groups,
D. Demeter, M. Allain, P. Leriche, I. Grosu I, J. Roncali, Tetrahedron Lett., 2010, 51, 4117-4120.
DOI: 10.1016/j.tetlet.2010.05.147
Synthesis of Podands with Cyanurate or Isocyanurate Cores and Terminal Triple Bonds,
F. Piron, C. Oprea, C. Cismaş, A. Terec, J. Roncali, I. Grosu, Synthesis, 2010, 1639-1644.
DOI: 10.1055/s-0029-1218724
Protein-inorganic Arrays Construction: Design and Synthesis of the Building Blocks,
N. D. Bogdan, M. Matache, V. M. Meier, C. Dobrotă, I. Dumitru, G. D. Roiban, D. P. Funeriu, Chem.-Eur. J., 2010, 16, 2170-2180.
DOI: 10.1002/chem.200902649
Selected Publications of the Organometallic Chemistry Group
Symmetry, aggregation and counterion role in tuning NIR absorbance of a Cu(I) coordination complex,
C. Cretu, A. A. Andelescu, A. Silvestru, V. Chiș, A. Candreva, M. La Deda, E. I. Szerb, Inorg. Chim. Acta, 2024, 572, 122302.
DOI: 10.1016/j.ica.2024.122302
C-H bond activation at antimony(III): synthesis and reactivity of Sb(III)-oxyaryl species,
G. Duneş, M. Cordier, S. Kahlal, A. Pöllnitz, J.-Y. Saillard, C. Silvestru, Y. Sarazin, Dalton Trans., 2024, 53, 15427-15440.
DOI: 10.1039/D4DT01400F
Orthopalladated imidazolones and thiazolones: synthesis, photophysical properties and photochemical reactivity,
D. Dumitraş, D. Dalmau, P. Garcia-Orduna, A. Pop, A. Silvestru, E. P. Urriolabeitia, Dalton Trans., 2024, 53, 8948-8957.
DOI: 10.1039/D4DT00730A
NCN-pincer organopnictogen(III) bis(aryloxides),
G. Duneş, C. Silvestru, New. J. Chem., 2024, 48, 5523-5529.
DOI: 10.1039/D3NJ05840A
Silver(I) complexes with diorganochalcogen ligands of type (2-MeC6H4CH2)2E (E = S, Se). Synthesis, structure and antiproliferative activity,
L. Corjuc, A. Pop, E. Licarete, M. Banciu, A. Silvestru, Inorg. Chim. Acta, 2024 , 565, 121972.
DOI: 10.1016/j.ica.2024.121972
On the coordination behaviour of diorganoselenium ligands based on amino and azole functionalities: silver(I) complexes with relevance for biological applications,
R. A. Popa, M. David, E. Licarete, M. Banciu, A. Silvestru, New J. Chem., 2022, 46, 23019-23029.
DOI: 10.1039/D2NJ04812D
Diaryllead(II) species stabilized by C,O-chelating ligands,
A.-A. Someșan, R. A. Varga, New. J. Chem., 2022, 46, 20074-20077.
DOI: 10.1039/D2NJ03796C
Supramolecular architectures in novel diphenyl(aryl)tin(IV) chlorides,
C. Afloarei, I. Barbul, A.-A. Someșan, C. Silvestru, R. A. Varga, Polyhedron, 2022, 222, 115894.
DOI: 10.1016/j.poly.2022.115894
Silver(I) and gold(I) complexes of multidentate ligands based on functionalized pyridine,
D. Dumitraș, A. Pop, A. Silvestru, Polyhedron, 2022, 220, 115801.
DOI: 10.1016/j.poly.2022.115801
New ionic [{2-(Me2NCH2)C6H4}(R)Sn{(EPPh2)2N}][(EPPh2)2N] (R = 2-(Me2NCH2)C6H4, nBu; E = O, S, Se) compounds. Solution behavior and solid state structure,
E Denes, L. Marangiu, M. Arca, V. Lippolis, A. Silvestru, J. Organomet. Chem., 2022, 963, 122282.
DOI: 10.1016/j.jorganchem.2022.122282
Group 12 metal complexes of mixed thia/aza and thia/oxa/aza macrocyclic ligands,
A. M. Hodorogea, A. Silvestru, V. Lippolis, A. Pop, Polyhedron, 2022, 216, 115650.
DOI: 10.1016/j.poly.2022.115650
Homoleptic and heteroleptic diorganoselenides containing pyrazole functionalities. Synthesis, characterization, and antioxidant activity,
R. A. Popa, A. Nicoară, M. Arca, V. Lippolis, A. Pintus, A. Silvestru, Appl. Organomet. Chem., 2022, 36, e6894.
DOI: 10.1002/aoc.6894
C,O-Chelated organotin(IV) derivatives as potential anticancer agents: Synthesis, characterization, and cytotoxic activity,
A.-A. Someșan, S.-M. Vieriu, A. Crăciun, C. Silvestru, P. Chiroi, A. Nutu, A. Jurj, R. Lajos, I. Berindan-Neagoe, R. A. Varga, Appl. Organomet. Chem., 2022, e6540.
DOI: 10.1002/aoc.6540
Organopnictogen(III) bis(arylthiolates) containing NCN-aryl pincer ligands: from synthesis and characterization to reactivity,
G. Duneş, A. Soran, C. Silvestru, Dalton Trans., 2022, 51, 10406-10419.
DOI: 10.1039/d2dt01436j
[2,6-{O(CH2CH2)2NCH2}2C6H3]SbCl2 – a new pincer ligand-containing organoantimony(III) compound. Molecular structure and supramolecular aspects,
G. Duneş, A. Soran, C. Silvestru, Rev. Roum. Chim., 2022, 67, 385-392.
DOI: 10.33224/rrch.2022.67.6-7.05
Reactivity of a carbonyl moiety in organotin(IV) compounds: novel Pd(II) and Cu(II) complexes supported by organotin(IV) ligands
A.-A. Someșan, C. Silvestru, R. A. Varga, New J. Chem., 2021, 45, 3817-3827.
DOI: 10.1039/d0nj06016j
Synthesis, structural characterization and in vitro antiproliferative effects of novel organotin(IV) compounds with nicotinate and isonicotinate moieties on carcinoma cells
S.-M. Vieriu, A.-A. Someșan, C. Silvestru, E. Licarete, M. Banciu, R. A. Varga, New J. Chem., 2021, 45, 1020-1028.
DOI: 10.1039/d0nj05069e
Synthesis, physicochemical properties, crystal molecular structure and DFT investigation of an organobismuth(III) bis(dimethyldithiocarbamate),
A. Anton, A. Soran, C. Silvestru, J. Mol. Struct., 2021, 1247, 131335.
DOI: 10.1016/j.molstruc.2021.131335
{2,6-Bis[(dimethylamino)methyl]phenyl}mercury(II) acetate, [2,6-(Me2NCH2)2C6H3]Hg(OAc) – a useful intermediate for selective palladation of 1,3-(Me2NCH2)2C6H4,
L. Kiss, S. Sergiu, M. Vlassa, A. Silvestru, C. I. Raț and C. Silvestru, Rev. Roum. Chim., 2021, 66(2), 167-177.
DOI: 10.33224/rrch.2021.66.2.07
Cu(II) and Ag(I) complexes of the pyrazole-derived diorganoselenide (pzCH2CH2)2Se. Synthesis, solid state structure and solution behavior,
R. A. Popa, V. Lippolis and A. Silvestru, Inorg. Chim. Acta, 2021, 520, 120272.
DOI: 10.1016/j.ica.2021.120272
Synthesis and characterization of ternary graphene oxide, MnFe2O4 nanoparticles, and PAMAM dendrons nanocomposite decorated with palladium as heterogeneous catalyst for nitroaromatics reduction,
A. Ramezanpour, K. Karami, M. Kharaziha, C. Silvestru and P. Bayat, Appl. Organomet. Chem., 2021, e6329.
DOI: 10.1002/aoc.6329
Silver(I) complexes based on diorganoselenium(II) ligands with amino or hydroxo functionalities,
M. David, R. Mitea, A. Silvestru, J. Mol. Struct., 2021, 1246, 131243.
DOI: 10.1016/j.molstruc.2021.131243
Hypercoordinated diorganopnicogen(III) compounds based on a butterfly-like skeleton of type [CH3OCH2CH2N(CH2C6H4)2]M (M = Sb, Bi),
R. Șuteu, A. M. Toma, M. Mehring, A. Silvestru, J. Organomet. Chem., 2020, 920, 121343.
DOI: 10.1016/j.jorganchem.2020.121343
Hypercoordinated diorganoantimony(III) compounds of types [2-(Me2NCH2)C6H4]2SbL and [PhCH2N(CH2C6H4)2]SbL (L = Cl, ONO2, OSO2CF3). Synthesis, structure and catalytic behaviour in the Henry reaction,
R. Şuteu, C. I. Raţ, C. Silvestru, A. Simion, N. Candu, V. I. Pârvulescu, A. Silvestru, Appl. Organomet. Chem., 2020, 34, e5393.
DOI: 10.1002/aoc.5393
Evaluation of bismuth-based dispersion energy donors – synthesis, structure and theoretical study of 2-biphenylbismuth(III) derivatives,
A.-M. Fritzsche, S. Scholz, M. Krasowska, K. Bhattacharyya, A. M. Toma, C. Silvestru, M. Korb, T. Rüffer, H. Lang, A. A. Auer, M. Mehring, Phys. Chem. Chem. Phys., 2020, 22, 10189-10211.
DOI: 10.1039/C9CP06924K
Group 12 metal complexes with P,N chelating triarylphosphanes. Solution behaviour and solid state structure,
A. Dobri, A. Covaci, A. Covaci, A. Silvestru, Polyhedron, 2020, 182, 114511.
DOI: 10.1016/j.poly.2020.114511
Tetra-(p-tolyl)antimony(III)-containing heteropolytungstates, [{(p-tolyl)SbIII}4(A-α-XW9O34)2]n− (X = P, As, or Ge): Synthesis, structure, and study of antibacterial and antitumor Activity,
T. Ma, P. Yang, I. Dammann, Z. Lin, A. S. Mougharbel, M.-X. Li, F. Adǎscǎliţei, R. Mitea, C. Silvestru, C. Thorstenson, M. S. Ullrich, K. Cseh, M. A. Jakupec, B. K. Keppler, M. Donalisio, R. Cavalli, D. Lembo, U. Kortz, Inorg. Chem., 2020, 59, 2978-2987.
DOI: 10.1021/acs.inorgchem.9b03322
Lead(II) siloxides,
A.-A. Someșan, E. Le Coz, C. I. Raț, V. Dorcet, T. Roisnel, C. Silvestru, Y. Sarazin, Chem. Eur. J., 2019, 25, 16236-16240.
DOI: 10.1002/chem.201904713
Coordination polymers and supramolecular solid-state architectures constructed from an organometallic tecton, bis(4-pyridyl)mercury,
T. Mocanu, L. Kiss, A. Sava, S. Shova, C. Silvestru, M. Andruh, Polyhedron, 2019, 166, 7-16.
DOI: 10.1016/j.poly.2019.03.020
Organoselenium compounds with N,C,N pincer groups. Synthesis, structure and reactivity,
A. Pop, A. Silvestru, Polyhedron, 2019, 160, 279-285.
DOI: 10.1016/j.poly.2018.12.041
Catalytic activity and facile recovery of a cyclometalated N-heterocyclic carbene palladium(II) complex immobilized by non-covalent interactions on reduced graphene oxide,
K. Karami, A. Ramezanpour, M. Zakariazadeh, C. Silvestru, Appl. Organomet. Chem., 2019, 33, e4907.
DOI: 10.1002/aoc.4907
Coordination polymers constructed from triorganotin(IV) nodes and fumarato spacers,
A. V. Ţopîrlan, A. A. Patrascu, A. Sava, D.-L. Popescu, C. Silvestru, I. Haiduc, M. Andruh, J. Organomet. Chem., 2019, 882, 58-63.
DOI: 10.1016/j.jorganchem.2018.12.021
New hypercoordinated diorganotin(IV) compounds with dithiocarbamato ligands. Synthesis and structural characterization,
N.Chiorean, C. Coza, A. Pop, A. Silvestru, J. Organomet. Chem., 2019, 880, 83-90.
DOI: 10.1016/j.jorganchem.2018.10.030
Experimental evidence for hypercoordination in triorganotelluronium halides with 2-(Me2NCH2)C6H4 groups,
A. Beleagă, E. Denes, C. Silvestru, A. Silvestru, New J. Chem., 2019, 43, 11585-11595.
DOI: 10.1039/C9NJ02530H
Aminofluoroalkoxide amido and boryloxo lead(II) complexes,
A.-A. Someșan, T. Roisnel, V. Dorcet, C. Silvestru, Y. Sarazin, Dalton Trans., 2019, 48, 9944-9948.
DOI: 10.1039/C9DT02110H
Reaction of imidazoline-2-selone derivatives with mesityltellurenyl iodide: a unique example of a 3c-4e Se→Te←Se three-body system embedding a tellurenyl cation,
M. C. Aragoni, M. Arca, A. J. Blake, E. Cadoni, L. O. Copolovici, F. Isaia, V. Lippolis, S. Murgia, A. M. Pop, C. Silvestru, J. P. Tidey, R. A. Varga, New J. Chem., 2019, 43, 11821-11831.
DOI: 10.1039/C9NJ01593K
Novel mono- and bimetallic organotin(IV) compounds as potential linkers for coordination polymers,
A.-A. Someșan, I. Barbul, S.-M. Vieriu, R. A. Varga, C. Silvestru, Dalton Trans., 2019, 48, 6527-6538.
DOI: 10.1039/C9DT00817A
New organotin(IV) bromides containing potential donor ligands. Synthesis, characterization and supramolecular architecture,
A.-A. Someșan, R. A. Varga, C. Silvestru, Inorg. Chim. Acta, 2018, 475, 177-183.
DOI: 10.1016/j.ica.2017.09.066
Synthesis and characterization of diorganoantimony(III) and -bismuth(III) halides with 2-(Et2NCH2)C6H4 and 2-(i-Pr2NCH2)C6H4 substituents,
I. Chircă, C. Silvestru, H. J. Breunig, C. I. Raţ, Inorg. Chim. Acta, 2018, 475, 155-160.
DOI: 10.1016/j.ica.2017.11.021
Triarylphosphanes with 2-(Et2NCH2)C6H4 groups. Copper(I) complexes and oxidation derivatives of type EP(C6H4CH2NEt2-2)nPh3-n (E = S, Se; n = 1,2),
R. Șuteu, S. Shova, A. Silvestru, Inorg. Chim. Acta, 2018, 475, 105-111.
DOI: 10.1016/j.ica.2017.09.044
Solid-state structure and solution behaviour of organomercury(II) compounds containing 2-(Me2NCH2)C6H4- moieties. Supramolecular aspects,
O. Cadar, A. Pöllnitz, D. Mărgineanu, C. Silvestru, Inorg. Chim. Acta, 2018, 475, 90-97.
DOI: 10.1016/j.ica.2017.09.002
Organoselenium compounds containing pyrazole or phenylthiazole groups: Synthesis, structure, tin(IV) complexes and antiproliferative activity,
R. A. Popa, E. Licarete, M. Banciu, A. Silvestru, Appl. Organomet. Chem., 2018, 32, e4252.
DOI: 10.1002/aoc.4252
Triphenylbismuth(V) di[(iso)nicotinates] – transmetallation agents or divergent organometalloligands? First organobismuth(V)-based silver(I) coordination polymers,
A. Ben Kiran, T. Mocanu, A. Pöllnitz, S. Shova, M. Andruh, C. Silvestru, Dalton Trans., 2018, 47, 2531-2542.
DOI: 10.1039/C7DT04516F
Chapter Four - C–H Bond activation mediated by inorganic and organometallic compounds of main group metals,
C. I. Raţ, A. Soran, R. A. Varga, C. Silvestru, Adv. Organomet. Chem., 2018, 70, 233-311.
DOI: 10.1016/bs.adomc.2018.07.003
Stable lead(II) boroxides,
A.-A. Someșan, E. Le Coz, T. Roisnel, C. Silvestru, Y. Sarazin, Chem. Commun., 2018, 54, 5299-5302.
DOI: 10.1039/C8CC02459F
(N,Se) and (Se,N,Se) ligands based on carborane and pyridine fragments – reactivity of 2,6-[(1′-Me-1′,2′-closo -C2B10H10)SeCH2]2C5H3N towards copper and silver,
A. Ilie, O. Crespo, M. C. Gimeno, M. C. Holthausen, A. Laguna, M. Diefenbach, C. Silvestru, Eur. J. Inorg. Chem., 2017, 2643-2652.
DOI: 10.1002/ejic.201700075
Bismuth⋯π arene versus bismuth⋯halide coordination in heterocyclic diorganobismuth(III) compounds with transannular N→Bi interaction,
A. M. Toma, A. Pop, A. Silvestru, T. Rüffer, H. Lang, M. Mehring, Dalton Trans., 2017, 46, 3953-3962.
DOI: 10.1039/C7DT00188F
Cadmium complexes bearing Me2N^E^O− (E = S, Se) organochalcogenoalkoxides and their zinc and mercury analogues,
A. Pop, C. Bellini, R. Şuteu, V. Dorcet, T. Roisnel, J.-F. Carpentier, A. Silvestru, Y. Sarazin, Dalton Trans., 2017, 46, 3179-3191.
DOI: 10.1039/C7DT00279C
Mapping the trajectory of nucleophilic substitution at silicon using a peri -substituted acenaphthyl scaffold,
E. Hupf, M. Olaru, C. I. Raţ, M. Fugel, C. B. Hübschle, E. Lork, S. Grabowsky, S. Mebs, J. Beckmann, Chem. Eur. J., 2017, 23, 10568-10579.
DOI: 10.1002/chem.201700992
Heterocyclic bismuth(III) compounds with transannular N→Bi interactions as catalysts for the oxidation of thiophenol to diphenyldisulfide,
A. M. Toma, C. I. Raț, O. D. Pavel, C. Hardacre, T. Rüffer, H. Lang, M. Mehring, A. Silvestru, V. I. Pârvulescu, Catal. Sci. Technol., 2017, 7, 5343-5353.
DOI: 10.1039/C7CY00521K
Mixed triorganobismuthines RAr2Bi [Ar = C6F5, 2,4,6-(C6F5)3C6H2] and hypervalent racemic Bi-chiral diorganobismuth(III) bromides RArBiBr (Ar = C6F5, Mes, Ph) with the ligand R = 2-(Me2NCH2)C6H4. Influences of the organic substituent,
M. Olaru, M. Nema, A. Soran, H. J. Breunig, C. Silvestru, Dalton Trans., 2016, 45, 9419-9428.
DOI: 10.1039/C5DT05074J
Tris(3-pyridyl)- and tris(4-pyridyl)phosphine chalcogenides and their complexes with ZnTPP (TPP = tetraphenylporphyrinate),
L. Dubován, A. Pöllnitz, C. Silvestru, Eur. J. Inorg. Chem., 2016, 1521-1527.
DOI: 10.1002/ejic.201501333
19-Tungstodiarsenate(III) functionalized by organoantimony(III) groups: tuning the structure-bioactivity relationship,
P. Yang, Z. Lin, G. Alfaro-Espinoza, M. S. Ullrich, C. I. Raţ, C. Silvestru, U. Kortz, Inorg. Chem., 2016, 55, 251-258.
DOI: 10.1021/acs.inorgchem.5b02189
Bismuth(III) cyclic compounds with transannular S→Bi interactions. An experimental and theoretical approach,
A. M. Toma, C. I. Raţ, A. Silvestru, T. Rüffer, H. Lang, M. Mehring, J. Organomet. Chem., 2016, 806, 5-11.
DOI: 10.1016/j.jorganchem.2016.01.019
Silver(I) complexes of a new multidentate macrocyclic ligand with N/S/Se donor atoms,
R. Popa, A. Silvestru, A. Pop, Polyhedron, 2016, 110, 197-202.
DOI: 10.1016/j.poly.2016.02.045
Synthesis and structural characterization of new functionalized bis(fluorenyl)stannane derivatives,
R. Septelean, P. M. Petrar, A. Pop, G. Nemeș, Polyhedron, 2016, 109, 154-160.
DOI: 10.1016/j.poly.2016.01.044
Bis(2-phenoxyphenyl)dichalcogenides and their chemical reactivity,
A. M. Toma, A. Nicoara, A. Silvestru, T. Rüffer, H. Lang, M. Mehring, J. Organomet. Chem., 2016, 810, 33-39.
DOI: 10.1016/j.jorganchem.2016.03.002
Hypervalent diorganoantimony(III) fluorides via diorganoantimony(III) cations - a general method of synthesis,
A. M. Preda, C. I. Raţ, C. Silvestru, H. Lang, T. Rüffer, M Mehring, RSC Advances, 2015, 5, 99832–99840.
DOI: 10.1039/c5ra21788a
Organoantimony(III)-containing tungstoarsenates(III): from controlled assembly to biological activity,
P. Yang, B. S. Bassil, Z. Lin, A. Haider, G. Alfaro-Espinoza, M. S. Ullrich, C. Silvestru, U. Kortz, Chem. Eur. J., 2015, 21, 15600–15606.
DOI: 10.1002/chem.201502398
Bis(4-pyridyl)mercury – a new linear tecton in crystal engineering: coordination polymers and co-crystallization processes,
T. Mocanu, C. I. Raţ, C. Maxim, S. Shova, V. Tudor, C. Silvestru, M. Andruh, CrystEngComm, 2015, 17, 5474–5487.
DOI: 10.1039/c5ce00388a
A general route to monoorganopnicogen(III) (M = Sb, Bi) compounds with a pincer (N,C,N) group and oxo ligands,
G. Strîmb, A. Pöllnitz, C. I. Raţ, C. Silvestru, Dalton Trans., 2015, 44, 9927–9942.
DOI: 10.1039/c5dt00603a
Diorganodichalcogenides and their intramolecular cyclization reactions,
A. Pöllnitz, A. Silvestru, Tetrahedron, 2015, 71, 2914–2921.
DOI: 10.1016/j.tet.2015.03.058
Synthesis, crystal structure and thermal decomposition kinetics of yttrium propionate,
M. Nasui, T. Petrisor Jr., R. B. Mos, A. Mesaros, R. A. Varga, B. S. Vasile, T. Ristoiu, L. Ciontea, T. Petrisor, J. Anal. Appl. Pyrolysis, 2014, 106, 92–98.
DOI: 10.1016/j.jaap.2014.01.004
Diorganochalcogen(II) ligands of type [R2C(OH)CH2](2-Me2NCH2C6H4)E (E = S, Se, Te; R = Me, Ph), and their silver(I) complexes,
A. Pop, R. Mitea, A. Silvestru, J. Organomet. Chem., 2014, 768, 121–127.
DOI: 10.1016/j.jorganchem.2014.06.007
Polyfluorinated functionalized m-terphenyls. New substituents and ligands in organometallic synthesis,
M. Olaru, J. Beckmann, C. I. Raț, Organometallics, 2014, 33, 3012–3020.
DOI: 10.1021/om500244y
On the coordination chemistry of organochalcogenolates RNMe2^E- and RNMe2^E^O- (E = S, Se) onto lead(II) and lighter divalent tetrel elements,
A. Pop, L. Wang, V. Dorcet, T. Roisnel, J.-F. Carpentier, A. Silvestru, Y. Sarazin, Dalton Trans., 2014, 43, 16459–16474.
DOI: 10.1039/c4dt02252a
Palladium(II) complexes with chiral organoantimony(III) ligands. Solution behavior and solid statestructures,
D. Copolovici, F. Isaia, H. J. Breunig, C. I. Raț, C. Silvestru, RSC Advances, 2014, 4, 26569–26576.
DOI: 10.1039/c4ra03482a
Organoselenium(II) halides containing the pincer 2,6-(Me2NCH2)2C6H3 ligand - experimental and theoretical investigation,
A. Pop, A. Silvestru, E. J. Juárez-Pérez, M. Arca, V. Lippolis, C. Silvestru, Dalton Trans., 2014, 43, 2221–2233.
DOI: 10.1039/C3DT52886C
Di(imino)aryltin(IV) dichlorides as potential tectons for heterometallic coordination compounds,
I. Barbul, R. A. Varga, K. C. Molloy, C. Silvestru, Dalton Trans., 2013, 42, 15427–15436.
DOI: 10.1039/c3dt52022f
Structural diversity of coordination cores in new homoleptic tetraaryltin(IV) dioxolane, aldehyde and imines. First octacoordinated double helicate tetraorganotin(IV) compound,
I. Barbul, R. A. Varga, C. Silvestru, Eur. J. Inorg. Chem., 2013, 3146–3154.
DOI: 10.1002/ejic.201300245
Hypervalent organoantimony and -bismuth compounds with pendant arm ligands,
C. I. Raţ, C. Silvestru, H. J. Breunig, Coord. Chem. Rev., 2013, 257, 818–879.
DOI: 10.1016/j.ccr.2012.07.026
Organoantimony(III) compounds containing (imino)aryl ligands of the type 2-(RN=CH)C6H4 (R = 2′,4′,6′-Me3C6H2, 2′,6′-iPr2C6H3): bromides and chalcogenides,
A. M. Preda, C. I. Raţ, C. Silvestru, H. J. Breunig, H. Lang, T. Rüffer, M. Mehring, Dalton Trans., 2013, 42, 1144–1158.
DOI: 10.1039/c2dt32494f
Synthesis, crystal structure and thermal decomposition of Zr6O4(OH)4(CH3CH2COO)12,
R. B. Mos, M. Nasui, T. Petrisor Jr., M. S. Gabor, R. A. Varga, L. Ciontea, J. Anal. Appl. Pyrolysis, 2012, 97, 137–142.
DOI: 10.1016/j.jaap.2012.06.010
The ring–chain tautomeric equilibria of selenium macrocyclic compounds: the isolation of the ring tautomer,
M. Bucsa, P. Alpar, R. A. Varga, A. Pirnau, A. Silvestru, M. Vlassa, Dalton Trans., 2012, 41, 4506–4510.
DOI: 10.1039/c2dt11749e
Synthesis and characterization of organoantimony(III)-containing heteropolytungstates,
M. Barsukova-Stuckart, L. F. Piedra-Garza, B. Gautam, G. Alfaro-Espinoza, N. V. Izarova, A. Banerjee, B. S. Bassil, M. S. Ullrich, H. J. Breunig, C. Silvestru, U. Kortz, Inorg. Chem., 2012, 51, 12015–12022.
DOI: 10.1021/ic301892s
Diorganodiselenides and zinc(II) organoselenolates containing (imino)aryl groups of type 2-(RN=CH)C6H4,
A. Pöllnitz, C. Silvestru, J.-F. Carpentier, A. Silvestru, Dalton Trans., 2012, 41, 5060–5070.
DOI: 10.1039/c2dt30098b
Synthesis, crystal structure and thermal decomposition study of a new barium acetato-propionate complex,
M. Nasui, R. B. Mos, T. Petrisor Jr., M. S. Gabor, R. A. Varga, L. Ciontea, T. Petrisor, J. Anal. Appl. Pyrol., 2011, 996, 445–449.
DOI: 10.1016/j.jaap.2011.08.007
Synthesis, crystal structure and thermal decomposition of a new copper propionate [Cu(CH3CH2COO)2]·2H2O,
M. Nasui, R. B. Mos, T. Petrisor Jr., M. S. Gabor, R. A. Varga, L. Ciontea, T. Petrisor, J. Anal. Appl. Pyrol., 2011, 996, 439–444.
DOI: 10.1016/j.jaap.2011.08.005
New group 11 complexes with metal – selenium bonds of methyldiphenylphosphane selenide: a solid state, solution and theoretical investigation,
A. Pop, A. Silvestru, M. C. Gimeno, A. Laguna, M. Kulcsar, M. Arca, V. Lippolis, A. Pintus, Dalton Trans., 2011, 40, 12479–12490.
DOI: 10.1039/c1dt11268f
An experimental and theoretical investigation on hypervalent organoselenium(II) halides: Case study of [2-(Et2NCH2)C6H4]SeX (X = Cl, Br, I),
A. Pöllnitz, V. Lippolis, M. Arca, A. Silvestru, J. Organomet. Chem., 2011, 696, 2837–2844.
DOI: 10.1016/j.jorganchem.2011.05.005
Formation of [Cp2TiSbMe2]2, [Cp2TiSb(SiMe3)2]2 and [Cp2TiCl]2·2Mes4Sb2,
H. J. Breunig, O. Moldovan, M. Nema, U. Rosenthal, C. I. Raț, R. A. Varga, J. Organomet. Chem., 2011, 696, 523–526.
DOI: 10.1016/j.jorganchem.2010.09.007
Organomercury(II) and -tellurium(II) compounds with the “pincer&rduquo; ligand 2,6-[O(CH2CH2)2NCH2]2C6H3 - stabilization of an unusual organotellurium(II) cationic species,
A. Beleagă, V. R. Bojan, A. Pölnitz, C. I. Raţ, C. Silvestru, Dalton Trans., 2011, 40, 8830–8838.
DOI: 10.1039/c1dt10414d
Group 12 metal aryl selenolates. Crystal and molecular structure of [2-(Et2NCH2)C6H4]2Se2 and [2-(Me2NCH2)C6H4Se]2M (M = Zn, Cd),
A. Pölnitz, A. Rotar, A. Silvestru, C. Silvestru, M. Kulcsar, J. Organomet. Chem., 2010, 695, 2486–2492.
DOI: 10.1016/j.jorganchem.2010.07.036
New chiral organoantimony(III) compounds containing intramolecular N→Sb interactions – solution behaviour and solid state structures,
D. Copolovici, V. R. Bojan, C. I. Raţ, A. Silvestru, H. J. Breunig, C. Silvestru, Dalton Trans., 2010, 39, 6410–6418.
DOI: 10.1039/c003318a
Study of the coordination abilities of stibine ligands to gold(I),
V. R. Bojan, E. J. Fernández, A. Laguna, J. M. López-de-Luzuriaga, M. Monge, M. E. Olmos, R. C. Puelles, C. Silvestru, Inorg. Chem., 2010, 49, 5530–5541.
DOI: 10.1021/ic1003484
Syntheses, solid-state structures, solution behaviour of hypervalent organobismuth(III) compounds [2-(Et2NCH2)C6H4]nBiX3-n and DFT characterization of [2-(Me2NCH2)C6H4]nBiX3-n [X = Cl, Br, I; n = 1 - 3],
A. Soran, H. J. Breunig, V. Lippolis, M. Arca, C. Silvestru, J. Organomet. Chem., 2010, 695, 850–862.
DOI: 10.1016/j.jorganchem.2010.01.004
Synthesis, crystal structure and thermal decomposition of [La2(CH3CH2COO)6·(H2O)3]·3.5H2O precursor for high-k La2O3 thin films deposition,
L. Ciontea, M. Nasui, T. Petrisor Jr., R. B. Mos, M. S. Gabor, R. A. Varga, T. Petrisor, Mater. Res. Bull., 2010, 45, 1203–1208.
DOI: 10.1016/j.materresbull.2010.05.019