Supramolecular Organic and Organometallic Chemistry Centre

TE 295 - Results

Published articles

• 2'-Iodo-2,2'',3,3'',4,4'',5,5'',6,6''-decamethyl-1,1':3',1''-terphenyl chloroform monosolvate.
  Olaru, M.; Roşca, S.; Raț, C.I. Acta Crystallogr., Sect. E: Struct. Rep. Online 2011, 67, o213.
  
  DOI: 10.1107/S1600536810052736
  
  
• (2,4,6-trimethylphenyl)boronic acid-triphenylphosphine oxide (1/1)
  Roşca, S.; Olaru, M.; Rat, C.I. Acta Crystallogr., Sect. E: Struct. Rep. Online 2012, 68, o31.
  
  DOI: 10.1107/S1600536811051609
  
  
• Hypervalent organoantimony and -bismuth compounds with pendant arm ligands
  Raț, C.I.; Silvestru, C.; Breunig, H.J. Coord. Chem. Rev. 2012, 257, 818-879.
  
  DOI: 10.1016/j.ccr.2012.07.026
  
  
• Polyfluorinated Functionalized Arenes: Starting Materials for Electron Deficient Bulky Ligands
  Olaru, M.; Raț, C.I.Organometallics 2014, 33, 3012-3020.
  
  DOI: 10.1021/om500244y
  
  
• Synthesis and structural characterization of substituted phenols with m-terphenyl backbone, 2,4,6-R₃C₆H₂OH (R = 2,4,6-Me₃C₆H₂, Me₅C₆).
  A. B. Şolea, M. Olaru, C. Silvestru and C. I. Raţ, Z. Naturforsch., B: Chem. Sci., 2014, manuscript accepted for publication.
  DOI: n.a.
  
  

Presentations at international conferences

• Organoantimony(III) and organobismuth(III) compounds with m-terphenyl substituents.
  Raț, C.I.
  at the Journées de chimie organométallique, supramoléculaire et catalyse ( Académie Roumaine), 14-15 April 2011, Bucharest, Romania. (oral presentation)
  
• Organobismuth(III) Dibromides: 2,6-Ar₂C₆H₃BiBr₂ (Ar = 2,3,5,6-Me₄C₆H, 2,3,4,5,6-Me₅C₆).
  Olaru, M.; Raț, C.I.
  at the XIX EuCheMS Conference on Organometallic Chemistry (XIX EuCOMC), 3-7 July 2011, Toulouse, France. (poster presentation)
  
  
• Organoantimony(III) Dibromides: 2,6-Ar₂C₆H₃SbBr₂ (Ar = 2,3,5,6-Me₄C₆H, 2,3,4,5,6-Me₅C₆)
  Roşca, S.; Raț, C.I.
  at the XIX EuCheMS Conference on Organometallic Chemistry (XIX EuCOMC), 3-7 July 2011, Toulouse, France. (poster presentation)
  
  
• Synthesis of Functionalized Polyfluorinated Arenes of Type 2,4,6-(C₆F₅)₃C₆H₂X (X= Cl, NO₂).
  Olaru, M.; Raț, C.I.
  at the 18^th International Symposium on Homogeneous Catalysis (XVIII ISHC), 9-13 July 2012, Toulouse, France. (poster presentation)
  
  
• Synthesis of 2,4,6-R₃C₆H₂X [X = NH₂, R = 2,4,6-Me₃C₆H₂; X = OH, R = 2,4,6-Me₃C₆H₂, Me₅C₆] by palladium catalyzed cross-coupling reactions.
  Şolea, A.
  at the 10^th International Conference "Students for Students" 10-14 April 2013, Cluj-Napoca, Romania. (oral presentation)
  Şolea, A. was awarded with one of the three prizes or the Romanian Society of Chemistry.
  
  
• Synthesis of Functionalized Polyfluorinated Arenes.
  Olaru, M.; Raț, C.I.
  at the International Symposium of the Romanian Catalysis Society (RomCat 2013), 29-31 May 2013, Cluj-Napoca, Romania. (poster presentation)
  
  
• Polyfluorinated Terphenyl Substituents. Synthesis and Applications.
  Olaru, M.; Beckmann, J.; Raț, C.I.
  at the Norddeutsches Doktorandenkolloquium, 19-20 September 2013, Bremen, Germania. (poster presentation)
  
  

Other presentations

• Starting Materials for Novel Bulky Aryl Ligands.
  Raț, C.I.
  presentation at the Bremen Universität Bremen in the group of Prof. Dr. Jens Beckmann, May 2013, Germany.
  
  

MSc, BSc or PhD theses developed within the project framework

• Olaru, M. Synthesis of Functionalized Polyfluorinated Arenes. MSc Thesis, Babes-Bolyai University, Cluj-Napoca, June 2012.
  
  
• Roşca, S. Synthesis and characterization of functionalized bulky arenes and of phenoxide complexes active in polymerization reactions of olefins and of lactones. MSc Thesis, Babes-Bolyai University, Cluj-Napoca, June 2012.
  
  
• Şolea, A. Synthesis and structural characterization of bulky phenols with m-tephenyl backbone. BSc Thesis, Babes-Bolyai University, Cluj-Napoca, June 2014.
  
  
• Olaru, M. Contributions to the organometallic chemistry of heavy pnicogens with bulk aryl substituents. PhD Thesis under development at Babes-Bolyai University, Cluj-Napoca, started in 2012.
  
  

Mobilities - career development of young researchers

• Roşca, S.
  Jan. - Jun. 2012, research stay in the group of Prof. Dr. Jean-François Carpentier,
  Institut des Sciences Chimique de Rennes, Rennes, France.
  The mobility was financially supported to a great extent through the Erasmus Student Mobility grant.
  
  
• Olaru, M.
  Jul. - Sep. 2013, research stay in the group of Prof. Dr. Jens Beckmann,
  Universität Bremen, Bremen, Germany.
  
  

Unpublished results

• Glimpse into the reductive elimination step of the cross-coupling reactions.
  Roşca, S.; Olaru, M.; Raţ, C.I. Chem. Commun., manuscript in preparation.
  
  
• Syntheses and caracterization of antimony(III) and bismuth(III) dibromides with m-terphenyl substituents.
  Roşca, S.; Olaru, M.; Raţ, C.I. J. Organomet. Chem., manuscript in preparation.
  
  

Reports

• The yearly scientific reports containing experimental details of unpublished compounds data can be provided for project evaluation purposes only. To obtain copies of these reports please contact Ciprian-Ionuţ Raţ by e-mail at ciprian.rat (at) ubbcluj.ro .